Defect-induced interfacial modulation for enhanced resistive switching performance in antiferroelectric/ferroelectric heterostructures

Resistive switching devices, particularly memristors, have attracted considerable interest due to their promising applications in neuromorphic computing and data storage. However, achieving high performance and reliability remains a significant challenge, especially in the optimization of their ferroelectric and switching properties. In this study, we report a substantial enhancement of both resistive switching and ferroelectric properties in NaNbO₃/PbTiO₃ multilayers, facilitated by interfacial modifications of the electronic structure induced by defects and strain. The well-defined interfaces and strain gradients within the PTO layers lead to substantial alterations in local electronic properties, including Ti 3d orbital hybridization and oxygen octahedral tilting. These structural modifications enhance charge trapping dynamics, resulting in an ON/OFF ratio of 10⁴, compared with 10² in single-layer NNO films. The synergistic effects of enhanced polarization and electronic state modulation are shown to optimize both the ferroelectric and resistive switching behaviors, highlighting the pivotal role of interface engineering in achieving high-performance memristive devices.