fig15

Catalyst design for the electrochemical reduction of carbon dioxide: from copper nanoparticles to copper single atoms

Figure 15. (A) Schematic diagram of CO2RR on Cu/Al2O3 SAC; (B) Electronic structure and (C) projected densities of states (pDOS) of d-orbitals with an aligned Fermi level of Cu/Al2O3 SAC and Cu/Cr2O3 SAC. Color code: Cu, brick red; Al, purple; Cr, gray; O, red. (Reproduced with permission[170]. Copyright 2021, American Chemical Society); (D) TEM images of CuO/TiO2-5 catalyst in low magnification; (E) Schematic diagram of CO2RR on CuO/TiO2-5 catalyst; (F) FEs for different products over various CuO/TiO2 catalysts at -0.85 V vs. RHE in CO2-saturated 0.5 M KHCO3 aqueous solution; (G) FEs for different products over CuO/TiO2-5 catalyst at various potentials. (Reproduced with permission[171]. Copyright 2018, MDPI, Basel, Switzerland). CO2RR: Carbon dioxide reduction reaction; SAC: Single-atom catalysts; FE: Faraday efficiency; RHE: Reversible hydrogen electrodes; TEM: Transmission electron microscope.

Microstructures
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