fig2

Cathode architecture and active site engineering in lithium-CO<sub>2</sub> batteries

Figure 2. (A) Formation mechanism of Li2CO3. (B) Growth mechanisms for Li2CO3/C products. (Reproduced with permission[3]. Copyright 2023, Wiley-VCH). (C) Formation mechanism of Li2O. (D and E) Galvanostatic discharge curves and corresponding product of the Li-CO2 battery under different capacities. (Reproduced with permission[21]. Copyright 2017, Elsevier). (F) Formation mechanism of Li2C2O4. (G) Solid RM(II)-BTC-catalyzed reaction mechanism towards Li2C2O4 pathway. (H) The CV curves of solid RM(II)-BTC and CNTs cathode in CO2 and Ar atmosphere. (I) Ex-situ FTIR spectra of solid RM(II)-BTC cathode. (Reproduced with permission[24]. Copyright 2024, Springer Nature). (J) Formation mechanism of HCOOH. (K) Comparison between aqueous and aprotic Li-CO2 batteries. (Reproduced with permission[27]. Copyright 2021, Wiley-VCH).

Microstructures
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