fig4

Na-deficient P2-type layered oxide cathodes for practical sodium-ion batteries

Figure 4. (A) Schematic illustration of structure, phase transitions, and corresponding reaction mechanisms for P2-Na0.67CoO2 and P2-Na0.6Co0.78Ru0.22O2; (B) Electrochemical performance of P2-Na0.67CoO2 and P2-Na0.6Co0.78Ru0.22O2. Reproduced with permission, Copyright 2023[70], Wiley-VCH; (C) Schematic illustration of the synthesis of P2-Na2/3Mn1/2Ni1/6Co1/3O2; (D) Cycling stability of P2-Na2/3Mn1/2Ni1/6Co1/3O2; (E) Schematic illustration of the phase transitions for P2-Na2/3MnxNix−1/3Co4/3−2xO2 (1/3 ≤ x ≤ 2/3). Reproduced with permission, Copyright 2021[77], Wiley-VCH; (F) Voltage profiles and electrochemical performance of Ti-substituted and Ti-Zn-substituted P2 cathodes; (G) Selected operando XRD patterns and schematic illustrations of structural change mechanisms for these cathodes. Reproduced with permission, Copyright 2023[86], Wiley-VCH.

Microstructures
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