fig9

Thermal expansion of FeNi Invar and zinc-blende CdTe from the view point of local structure

Figure 9. Schematic mechanism of the NTE in zinc-blend structure. (A) A cubic unit cell of zinc blende structure, (B) schematic view of the transverse acoustic vibrational mode around the X point in the Brillouin zone, and (C) look of atoms 1 and 2 along the Thermal expansion of FeNi Invar and zinc-blende CdTe from the view point of local structure axis. In (B), the vibrational motions of atoms 1 and 2 are in antiphase. In (C), R0 and R (R0 and R’) in the left (right) are initial (relaxed) equilibrium and instantaneous interatomic distances, respectively. Due to the vibrational instability, the lattice is consequently contracted.

Microstructures
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