fig7
Figure 7. (A) Vibrational sum-frequency-generation spectra of water molecules at the water-graphene interfaces[12]; (B) Schematic diagrams of interfacial water structures on CaF2 substrate and on CaF2-supported graphene with varying layer numbers[12]; (C) Correlation between wettability implied by VSFG spectra and water-graphene adhesion energy based on WCA[13]; (D) Thermal desorption spectroscopy curves of graphene grown on Cu (top panel) and bare Cu (bottom panel) at sub-monolayer coverages; Insets in the figures represent the corresponding macroscopically measured WCA[120]. Figures are adapted from references[12,13,120] with permission. VSFG: Vibrational and frequency generation; WCA: water contact angles.