fig5

PGM-free carbon-based catalysts for the electrocatalytic oxygen reduction reaction: active sites and activity enhancement

Figure 5. (A) Graphical illustration of typical N species in nitrogen-containing graphitic and corresponding binding energies of XPS as marked. Reproduced from Yang et al.[104] by permission from Wiley-VCH. (B) LSV curves of CNTPPA (i), CNTP4VP (ii), CNTPMPy (iii), CNTPMVI (iv), CNTPPP (v), and Pt/C (vi). Reproduced from Rao et al.[106] by permission from the American Chemical Society (ACS). (C) LSV curves of different NC catalysts. Reproduced from Li et al.[107] by permission from Elsevier. (D) Schematic diagram of ΔG for the three nitrogen-doped configurations in the first electron reduction process and plot of specific activity versus cycling number for graphite N. Reproduced from Wang et al.[109] by permission from ACS. (E) ORR-catalyzed cycle for the conversion of graphitic N to pyridine N. Reproduced from Kim et al.[111] by permission from RSC.

Energy Materials
ISSN 2770-5900 (Online)
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