fig4

Design strategy towards flame-retardant gel polymer electrolytes for safe lithium metal batteries

Figure 4. (A) Mechanism for polymerization of VC. (B) TG analysis of different electrolytes in FRSE electrolyte system. This figure is quoted with permission from Tan et al.[69] (C) Digital image of the quasi-solid electrolyte membrane. This figure is quoted with permission from Chen et al.[71] (D) Microstructure, thermotolerance and flammability of the P(AN-DEVP)-based membrane. Thermal shrinkage of PAN and P(AN-DEVP) membranes. (E) Burning tests of PAN-GPEs and PA1D1-GPE. This figure is quoted with permission from Long et al.[72] (F) Possible flame-retardant mechanisms of NGPE; polymerized BCPN would release PO· radicals when heated, blocking the exothermic chain reactions. The inert gases, the decomposition products of polymerized BCPN (for example, N2), further inhibit the combustion process. R1 and R2 represent alkyl chains of ethers. (G) Voltage changes and the corresponding infrared thermal imaging photographs of fully charged Li||1 M LiPF6 in EC:DMC||NCM811 and Li||NGPE||NCM811 pouch cells during nail penetration tests. (H) LSV curves and the corresponding infrared thermal imaging photographs of Li||1 M LiPF6 in EC:DMC||NCM811 and Li||NGPE||NCM811 pouch cells at a scan rate of 20 mV s-1 from the open circuit voltage to 10 V. This figure is quoted with permission from Meng et al.[16].

Energy Materials
ISSN 2770-5900 (Online)
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