fig3

Figure 3. (A) Macroscopic chiral spherulites (≈ 1 mm) formed by co-assembling LC-BCP, RhB, and chiral TA, illustrating their evolution; (B) The CPL and g_lum spectra of annealed films LC-BCP/L-TA/RhB and LC-BCP/D-TA/RhB were analyzed, elucidating the molecular and assembly structural alterations induced by UV irradiation and subsequent thermal re-annealing. Reproduced with permission from^[46]. Copyright 2023, Wiley-VCH. GmbH; (C) The chemical configurations of molecular switches (S, R, S)-switch 1 and (R, R, R)-switch 2 were depicted, illustrating their respective helical handedness and CPL signals within the CLC system upon light irradiation; (D) Message encryption and decryption employing dual-mode fluorescence and CPL. Reproduced with permission from^[47]. Copyright 2023, Wiley-VCH. GmbH. LC-BCP: Liquid crystal block copolymer; RhB: Rhodamine B; TA: tartaric acid; CPL: circularly polarized luminescence; CLC: cholesteric liquid crystal.