fig6

Organic cage-based frameworks: from synthesis to applications

Figure 6. (A) Crystal structures of OCF-32, OCF-33, and OCF-34 synthesized through the halogen bond[71]. Copyright 2022, Royal Society of Chemistry; (B) Schematic illustration of the synthesis of OCF-35 with the unique host-in-host structure through the electrostatic interaction; (C) Solid-state 13C CP-MAS NMR spectra of OCF-35; (D) FT-IR spectra of OCF-35; (E) N2 sorption isotherm at 77 K and the NLDFT pore size distribution plot (inset) of OCF-35. (B-E) were reproduced with permission[72]. Copyright 2022, Nature Publishing Group. OCF: Organic cage-based framework; CP-MAS: cross-polarization magic-angle spinning; NMR: nuclear magnetic resonance; FT-IR: Fourier-transform infrared spectra; NLDFT: nonlocal density functional theory.

Chemical Synthesis
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