fig5

Recent progress on metal-organic framework-based separators for quasi-solid-state lithium metal batteries

Figure 5. (A) Integrating TFSI-based ionic liquid into a garnet-like Li6.75Al0.25La3Zr2O12 (LALZO) framework for better ion transport and suppression of lithium dendrite formation; (B) The development of MOF-based QSSEs; (C) PEO-based QSSE for high-performance NMC622//Li batteries; (D) Constructing PTFE@LATP composite solid electrolytes with three-dimensional network for high-performance lithium batteries; (E) Schematic illustration of the porous LATP-PVDF-HFP membrane preparation process and the in-situ polymerization; (F) Isostructural Li-MOF expansion for high ionic conductive QSSE. (A) is quoted with permission from Kaur et al.[128]; (B) from Lin et al.[130]; (C) from Homann et al.[132]; (D) from Wang et al.[133]; (E) from Liu et al.[134]; and (F) from Butreddy et al.[136]. MOF: Metal-organic frameworks; QSSEs: quasi-solid-state electrolytes; PEO: polyethylene oxide; PTFE: polytetrafluoroethylene; LATP: lithium aluminum titanium phosphate; TFSI: trifluoromethylsulfonyl; PVDF: polyvinylidene fluoride; HFP: hexafluoro propylene.

Energy Materials
ISSN 2770-5900 (Online)
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