fig7

Fluorine chemistry in lithium-ion and sodium-ion batteries

Figure 7. (A) Schematic diagram of the mechanism of SEI and CEI formation. This figure is quoted with permission from Goodenough et al.[81]. (B) Schematic of how LiF-rich SEI prevents the growth of dendrites. This figure is quoted with permission from Choudhury et al.[82]. (C) The schematic shows that when heated, the fluoropolymer, CYTOP, gradually breaks down to release pure F2 gas. This gas then reacts with lithium metal or LixSi, resulting in a uniform and dense coating of LiF. This figure is quoted with permission from Zhao et al.[84]. (D) Long-term cycling stabilities of anode at a current rate of 0.2 A g-1 in 1m NaClO4 electrolyte in PC without and with 2 vol.% of FEC additive. This figure is quoted with permission from Wen et al.[88]. (E) Coulombic efficiency of Li||Cu battery at a current density of 0.10 mA cm-2. This figure is quoted with permission from Zhang et al.[86]. (F) Discharge capacities of the Li/LCO cells cycled at 1.0 C (1 C = 274 mA g-1). This figure is quoted with permission from Lee et al.[85].

Energy Materials
ISSN 2770-5900 (Online)
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