fig2

PGM-free carbon-based catalysts for the electrocatalytic oxygen reduction reaction: active sites and activity enhancement

Figure 2. (A) LSV curves of Pt/C and M-N-C. (B) Percentage of HO2- productivity of M-N-C. (C) Numbers of electron transference of M-N-C. (D) The U1 and U2 on various square planar active sites are graphed as a function of O binding energy, where the U1 represents the potential for four-electron ORR and U2 for two-electron ORR. (E) U1 and U2 of the ORR procedure are graphed as a function of O binding energy on metal centers of all possible square pyramids, producing a high active plateau area, while the medium binding energy is about 0 eV. Reproduced from Zheng et al.[56] by permission from Elsevier. (F) E1/2 of M-N-C electrocatalysts based on various metals were tested by LSV. Reproduced from Peng et al.[57] by permission from the American Chemical Society.

Energy Materials
ISSN 2770-5900 (Online)
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