fig6

Recent advances in the type, synthesis and electrochemical application of defective metal-organic frameworks

Figure 6. (A) Mixed linker approach in Ru-HKUST-1 leads to modified node defects. Reproduced with permission[126]. Copyright 2014, Wiley-VCH. (B) PCN-134 formed by 6-connected Zr 6 cluster, BTB, and TCPP. Reproduced with permission[127]. Copyright 2016, American Chemical Society. (C) Schematic illustration of defect formation by thermal decomposition of labile linker. Reproduced with permission[128]. Copyright 2017, American Chemical Society. SEM images of MTV Uio-66, (D) UiO-66(3A:1B), (E) UiO-66(1A:1B), (F) UiO-66(1A:3B), (G) UiO-66(3A:1C), (H) UiO-66(1A:1C) and (I) UiO-66(1A:3C). Reproduced with permission[130]. Copyright 2021, Elsevier. (J) The XRD patterns of ZIF-8-SV-5 μm and ZIF-8-SP-5 μm (insert SEM images). Reproduced with permission[131]. Copyright 2017, Elsevier. SEM images of UIO-66 with different synthesized conditions, (K) Zr-H-2 h, (L) Zr-H-10 h, (M) Zr-H-120 °C, (N) Zr H-140 °C. Reproduced with permission[132]. Copyright 2021, Wiley.

Energy Materials
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